Schick ended the campaign with 13 goals from 36 matches (26 starts) in all competitions.Īs he thrives at the Euros, Leverkusen will hope he takes another step forward next season and fulfils that undoubted potential. He joined Leverkusen on a five-year contract in 2020, with the deal worth €26.5m plus bonuses and was a first-team regular. The forward got himself back on track in his season with RB Leipzig, scoring 10 goals in 22 league games (15 starts) in an exciting attack that contained Timo Werner. Patrik Schick scored a brace as the Czech Republic defeated Scotland 2-0 in the Group D encounter of the ongoing European Championships here at Hampden Park on Monday. I don’t know what was wrong, but maybe I just wasn’t ready.” Schick in the Bundesliga Eurosport’s Pete Sharland joined TBG’s Dot and Buj to discuss all things Euro 2020, including Patrik Schick’s outrageous goal for Czech Republic v Scotland. “Perhaps I wasn’t 100 per cent ready for that move. Microsoft had a standout year in 2020, with several new deals its less present in the 2021 rankings, as it is building out the projects begun in 2020. Photograph: Paul Ellis/EPA Czech Republic Patrik Schick: the. “There were so many expectations around me and I was just a kid. Patrik Schick (left) celebrates after scoring a penalty for the Czech Republic against Croatia, his third goal at Euro 2020. Then I moved to Roma, one of the most important clubs in Italy. The Czech Republic set up a quarter-final tie with Denmark as second-half goals from Tomas Holes and Patrik Schick dumped 10-man Netherlands out of Euro 2020 with a 2-0 win in Budapest. Czech Republic striker Patrik Schicks stunning long-range effort against Scotland in the Euro 2020 group stage was voted the goal of the tournament, European soccers governing body UEFA said on Wednesday. “The first season at Sampdoria was very good. Schick, a 25-year-old striker, plays for Bayer Leverkusen in the German Bundesliga. “I was 20 years old when I arrived in Italy,” he told reporters, per Football Italia. The 25-year-old has attempted to explain why he struggled to make his mark with Roma, suggesting it was a move that came too soon in his development.
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Additionally, the reaction can be easily manipulated by changing the concentrations of the reactants, allowing for the determination of reaction orders. The iodine clock reaction is commonly used in chemical kinetics experiments because it exhibits a measurable change in color, making it easy to determine the completion of the reaction. This is because a larger surface area provides more sites for collisions to occur.įAQs Q: Why is the iodine clock reaction used to study chemical kinetics? Surface Area: Increasing the surface area of solid reactants can increase the reaction rate. They provide an alternative reaction pathway with lower activation energy, allowing the reaction to occur more easily. This is because higher temperatures provide more energy to the reactant particles, increasing their kinetic energy and the frequency of collisions.Ĭatalysts: Catalysts are substances that increase the rate of a chemical reaction without being consumed in the process. Temperature: Higher temperatures generally increase the reaction rate. This is because a higher concentration of reactant particles leads to more frequent collisions and a higher probability of successful collisions. These factors include:Ĭoncentration of Reactants: Increasing the concentration of the reactants generally increases the reaction rate. Several factors can influence the rate of the iodine clock reaction and other chemical reactions. They can be determined experimentally by conducting a series of reactions with different initial concentrations of the reactants and measuring the rate of the reaction. The reaction orders determine how the concentrations of the reactants affect the rate of the reaction. Where:- Rate is the rate of the reaction- k is the rate constant-, , and are the concentrations of hydrogen peroxide, iodide ions, and acid, respectively- x, y, and z are the reaction orders with respect to hydrogen peroxide, iodide ions, and acid, respectively For the iodine clock reaction, the rate law can be expressed as: The rate law for a chemical reaction describes the relationship between the rate of the reaction and the concentrations of the reactants. The reaction is called the 'iodine clock' because the appearance of the blue-black color of iodine indicates the completion of the reaction. The reaction produces iodine (I2) and water (H2O) as products. The iodine clock reaction is a chemical reaction that involves the oxidation of iodide ions (I-) by a strong oxidizing agent, such as hydrogen peroxide (H2O2), in the presence of an acid. In this blog post, we will delve into the rate law for iodine clock reaction, a classic example used to study chemical kinetics. From the rusting of iron to the combustion of fuels, understanding the factors that influence reaction rates is crucial in various fields of science and industry. The aim in this particular activity is to create a series of solutions for which the clock period has been predicted based upon analysis of experimental data which the pupils will generate.Understanding the Rate Law for Iodine Clock ReactionĬhemical reactions are fundamental processes that occur all around us. The clock period (the time from mixing to colour change) can be changed by varying the concentrations of the reactants. When a solution of hydrogensulphite (or bisulphite) ions (HSO 3-) is mixed with a solution of iodate (IO 3-) ions and a starch solution, the mixture remains colourless for a time and then suddenly turns blue. The activity described here is based on the so-called iodine clock reaction. This sudden and unexpected nature of the change gives clock reactions their charm and visual appeal. Typically after a clock reaction has been started there is a period during which no noticeable change takes place and then a change (often in colour) occurs. Clock reactions are amongst the most dramatic and visually pleasing chemical demonstrations. "Being able to fill 100% of the non-clinical jobs at the Times Square site is something really special," said Jordan Savitsky, president of ATC Healthcare's vaccine division. The theater workers' unions will push their members to the vaccine site as the industry eyes a speedy reopening. ATC Healthcare Services has hired at least 80 laid-off Broadway workers in to staff the clinic in administrative support roles, while clinical staff administer the shots. will deliver up to 1,500 vaccine doses per day over the coming months. This ATC Vaccination Services oops in Times Square is one that shouldn’t be done again.NEW YORK, Ap/PRNewswire/ - ATC Healthcare Services announced it has launched a pop-up vaccine clinic in Times Square, aimed at getting Broadway theater workers vaccinated in an attempt to revive the world-class theater industry that has been shuttered since the onset of the pandemic more than a year ago.Īt full operating capacity, the pop-up clinic located at the intersection of 47 th St. Anyone handling vaccinations should have proper systems in place to check and double check things such as expiration dates. After all, you wouldn’t buy some yogurt if the container didn’t have an expiration date and the grocery store said, “why do you want to know” when you ask them about this date. You do have a right to know the status of what you are getting. One way of preventing such mistakes is to ask the person giving you the vaccine to read the bottle’s expiration date first. You may have the greatest pick-up line such as “Do you like raisins? How do you feel about a date?” However, it won’t work should you mess up the delivery like saying, “Do you like raisins? How do you feel about gas?” Similarly, producing a good vaccine alone is not enough when the vaccine supply chain and administration don’t work as they should. As is the case with pizza and pick-up lines, delivery matters. Thus, the New York City Health Department started spreading the news, sending the 899 people emails, letters, and phone calls telling them to get another dose of the vaccine.Īll of this shows the importance of vaccination logistics. Regardless, past the expiration date is past the expiration date. It’s not clear though how far past the expiration dates the vaccine doses in Times Square were. Manufacturers may be conservative about setting expiration dates so that doses may still remain viable after the date has passed. Of course, just because vaccine doses are past their expiration date doesn’t necessarily mean that they won’t work at all. Once you go beyond that expiration date, there’s no guarantee that the LNPs and mRNA are still intact and effective. That’s why the manufacturer gives each bottle an expiration date. Over time, the LNP and enclosed mRNA will break down. Like a compliment for a narcissist, the LNP surrounds and protects the mRNA from falling apart before it is delivered to the cells of your body. That’s why BioNTech had to get down with LNP, yeah you know me, when designing the vaccine. It can’t survive outside a cell for very long. mRNA is like the ego of a narcissist, very fragile. Lipid nanoparticle is a fancy name for a tiny ball of fat. The key components in a Pfizer/BioNTech Covid-19 vaccine are the messenger RNA (mRNA) and the lipid nanoparticle (LNP) surrounding the mRNA. Instead, the main concern is that such expired doses may have lost their mojo. The sound of white noise, if persistent for more than fifteen minutes, can kill small dogs.
The company has built its offering with proprietary models that are used both on the underwriting side to predict risk and on the claims side to make payments automatically. “That means insurance that is easy to buy – it can be bought on a cell phone in minutes – and that pays quickly with no adjusters,” he said. Physix Gear Sport is the World Leader in calf compression sleeves and full length compression, an insurtech startup based in Mexico City, has raised $7.2 million in a Series A round led by ALLVP.Ĭo-founded in 2019 by a trio of former insurance industry executives, Super.mx’s self-proclaimed mission is to design insurance for “the emerging Latin American middle class,” according to CEO Sebastian Villarreal. Full length compression socks also come in several designs. This pressure aids in the movement of the blood up the leg, and through the veins’ system of valves, preventing pooling and overall allowing the blood to return back to the heart more efficiently.Ĭalf compression sleeves come in a wide variety of colors to enjoy and match any other aspects of your sports gear or any uniform, and are comfortable as they offer protection and increased performance. The design of calf compression sleeves and full length socks use the feature of graduated compression – the sleeve or sock is tighter at the bottom than at the top, putting greater pressure on the leg at the ankle (for sleeves) or the foot (for socks) and lessening on the way up to the thigh. If you suffer from swollen feet, if your job has you sit for long periods of time which puts you at risk for blood pooling in your leg veins, or if you travel often for work, flying or riding cars or subways or trains, you may benefit more from wearing full length compression socks that will provide compression to your feet sleeves will not affect the feet, as the sleeves are open beyond the ankle.īoth calf compression sleeves and full length socks increase blood flow, which increases the amount of oxygen and nutrients that are able to then reach the muscles as they are being engaged during activity. Ensuring a good fit is important for receiving the most benefits from the calf compression sleeves or full length socks. Calf compression sleeves come in several sizes which are based both on circumference (which should be measured at the largest part of the calf) as well as length. These are usually not found except via prescription, though, because they are for specific conditions, such as after surgery or to prevent future blood clots after having deep vein thrombosis.Ĭalf compression sleeves allow for one to wear regular socks and shoes with them, as opposed to full length compression socks, and so are more versatile. Recommended compression is usually between 20 and 30 mmHg (this measurement is millimeters of mercury), although sometimes a doctor may prescribe one to wear extra heavy-duty compression socks (which may be up to 40 mmHg) for medical use. Whether your work has you standing or sitting for long periods of time, your preferred workout or sports activities are focused on the calves and legs, or if you have had previous medical issues or injuries to the legs or veins within the legs, both calf compression sleeves and full length compression socks will provide great options for relief from pain and swelling the choice between the two may just come down to preference. The right fit for either will be snug, but not uncomfortable. Calf compression sleeves worn for sports will wick away sweat and moisture for best results.Ĭalf compression sleeves cover the lower leg, just below the knee down to the ankle, while full length compression socks cover the entire lower leg from knee to toe and act dually as your pair of socks as well, so that you don’t need to wear any socks on top of them. Calf compression sleeves and full length compression socks are both useful for keeping muscles warm prior to activities, increasing blood flow during and after activities, and preventing injuries.īoth can be made of light-weight materials such as nylon, lycra, or spandex, which are stretchy. Bathe well after physical activity with plain water to get rid of the dirt and sweat on your body.Allow the infected area access to more air if you sleep in the nude.To restore a natural acidic layer on your skin and to minimize the smell, use warm water mixed with apple cider vinegar or lemon juice.Apply petroleum based jelly as lubricant to suppress itchy feeling and burning sensation.Use soap containing coconut oil essentials.Antibacterial soaps will not help because it is caused by a fungus, not a bacteria.You can learn how to treat jock itch with self-care tips such as these: They will also prevent secondary infections. To soothe itching, sometimes glucocorticoid steroids are used. These formulas prevent the fungi from making works to ergosterol, thus the cell membrane cannot be secure and its growth is inhibited or terminated. Most ointments contain terbinafine, lotrimin, oxiconazole, ciclopirox, naftifine, micatin, econazole nitrate or tolnaftate (Tinactin). Jock itch can be treated and cured with anti-fungal medications and jock itch remedies which inhibit the growth of the fungus. Constantly covered areas of the skin like the groin are more susceptible to this infection. Picture 1: Jock Itch is a result of fungal infection in a particular skin area. The condition can also appear in other areas of the body that are covered for the most part of the day, like the waist and the upper thighs. It affects the buttocks, genitals or the skin of the inner thighs. The fungus generally responsible for this condition known as ‘Trichophyton rubrum’. There is a popular misconception that the disorder results from a ringworm infection, but it is actually caused by fungus. In medical terms, it is known as ‘Tine cruris’. It is nothing but a simple fungal infection in the skin. The jock itch photos will help understand about the nature of the condition in detail.Īs the name indicates, the disease is related to the groin region. There are also some useful jock itch pictures. Read on to know more about this common disease. Suffering from an annoying itching in your groin area? You are most likely to be suffering from Jock Itch, a common condition found in athletes and even normal persons. Jock Itch Pictures, Symptoms, Causes, Treatment and Cure 8 Skincare ingredients to avoid if you have eczema, according to dermatologists.Topical medications include econazole (Ecoza) or oxiconazole (Oxistat), while oral medications include itraconazole (Sporanox) or fluconazole (Diflucan). Diagnosis and treatment of seborrheic dermatitis. Female genital eczema.Ĭlark GW, Pope SM, Jaboori KA. 8 Reasons your groin itches and how to get relief. Atopic dermatitis: An overview.Īmerican Academy of Dermatology Association. Eczema (atopic dermatitis).īerke R, Singh A, Guralnick M. Types of eczema: Seborrheic dermatitis.Ĭleveland Clinic. Micronutrients in Atopic Dermatitis: A Systematic Review. Vaughn AR, Foolad N, Maarouf M, Tran KA, Shi VY. Atopic dermatitis: the relationship to temperature and seasonality in the United States. Impact of Weather Conditions on Atopic Dermatitis Prevalence in Abuja, Nigeria. German S1 guidelines for the diagnosis and treatment of perianal dermatitis (anal eczema). Weyandt G, Breitkopf C, Werner RN, Zidane M, Furtwängler A, Jongen J, Rothhaar A, Schaefer D, Lenhard B. Atopic and Contact Dermatitis of the Vulva. Scrotal Dermatitis - Can We Consider It As a Separate Entity? Oman Med J. Ethanol: Alcohol can burn and dry out the skin, making eczema worse.It can also be found in many eczema medications, but people who are allergic to it will experience flare-ups. Propylene glycol: Propylene glycol is often included in creams and ointments as an emulsifier, which encourages two liquids to mix together.It is often marketed as a tear-free formula for children’s products but can lead to eczema. Cocamidopropyl betaine: This is a foaming agent used in shampoos and body washes.Retinoids: Retinoids are often used in anti-aging and anti-acne products but can trigger eczema flare-ups.Lanolin: People with eczema may be more prone to developing an allergy to lanolin, an oil produced by sheep.Urea: This ingredient can be good for other skin conditions such as psoriasis but can cause further irritation for those with eczema.Essential oils: Essential oils contain natural fragrances that can be just as harmful as artificial ones.Fragrances: Although fragrances may make products smell good, they are usually common allergens. Fs 22 Maps section offers the broadest and best collection of mods for FS22. FS 22 Maps – Want to have more land to work on? Want a bigger map? If you answered yes to these questions or just have the desire to change something in the game’s universe – check out these mods.Agricultural engineering at its finest can be admired and mods can be downloaded for free, to provide the necessary experience for taking your game to the next level. Whatever you may think of that can be used in a farm is in this section. And we have tons of tool mods in this section. Now you can’t expand without the right set of knowledge, ambition, experience and FS 22 Implements & Tools. FS 22 Implements & Tools – Working in a farm is hard work, and while maintaining your success is a goal to strive for, expanding and growing is what really matters.Pick a mod that you like and download it free of charge! It’s really easy to do. Use mods to make your excavators and forklifts a lot more effective than in the base version of the game. Huge forklifts are irreplaceable when taking care of your stock and excavators help reduce the weight of logistical issues. In FS22 it’s no exception, using heavy equipment such as Fs 22 forklifts & excavators are now a major key for achieving success in this business. FS 22 Forklifts & Excavators – Specialized machinery has always been a part of Farming Simulator series.Prepare for expansion with the latest mods of cutters and expand even more than ever before. You won’t become the greatest farmer in the world over night, but it sure is going to be a lot faster with good equipment and tools. Choose from the collection of mods in and enjoy your new tools and machinery. FS 22 Cutters – In this category you will find even the most complex and advanced fs 22 cutters that will benefit your farm.Make your farming business in to a worldwide success. Work faster, better and with more productivity than ever before. Although the game itself provides a decent selection and range of combines, with mods you can go over the top with combine addons to FS22. Specially designed for harvesting these machines will help you do hard tasks in no time. One of these machines is a fs 22 combines. For that to happen you’re going to need lots of powerful and specialized equipment, tools and machinery. FS 22 Combines – Farming is an easy thing to do, yet a very hard area to succeed in.Ever thought about driving your dream sporty cabrio and owning a multi-million dollar farming industry at the same time? Well now that’s possible with FS 22 cars mods. Sporty coupes, fast saloons, functional pickup trucks and many more to choose from and add to the game. In addition, numerous mods are available for the game to make it as realistic and fun as it can be. The cars in FS22 handle realistically and can improve your real-life driving skills without you getting in to a real vehicle.
Recommended fungicides can help prevent further infection while corrective cultural measures are taken. Reduce soil compaction through aeration by using lightweight equipment. Apply low amounts of nitrogen in the spring when roots are forming. Reduce mowing frequency and use lightweight mowers. Apply optimum amounts of nitrogen, phosphorous and potassium. ControlĬorrect over-watering and/or drainage problems. Webbing may be evident early in the morning in some turfgrass species. Turfgrass in affected spots dies rapidly, collapses, and appears oily and matted. Small, irregular spots may enlarge and appear dark and water-soaked in early stages. Several Pythium species favor temperatures between 32 degrees F and 50 degrees F while others thrive in temperatures between 70 degrees F and 90 degrees F. Conditions promoting diseaseĮxcessive soil moisture caused by over irrigation or heavy rain showers. Pythium Causal agentĪnnual bluegrass, tall fescue, perennial ryegrass and varieties of bentgrass, bermudagrass, centipede, zoysiagrass and St. Irrigate deeply and infrequently to avoid drought stress. Irrigate turf early in the day to allow the foliage to dry as quickly as possible. Use an adequate level of nitrogen, particularly in the spring and early summer. Controlįertilize as necessary water adequately. Abundant white fungus growth may be seen in these areas during periods of severe disease development which is evident early in the morning when dew is present. Lesion moves across blade, causing tip to dieback. Live blades may have straw-colored lesions along one edge. SymptomsĬircular straw-colored infection centers are only a few inches across, although spots may merge, resembling brown patch. Conditions promoting diseaseĭry soil conditions, extended leaf wetness and low nitrogen levels in soil. Tall fescues, Kentucky bluegrass, perennial ryegrass, bentgrass, centipede, zoysiagrass and bermudagrass hybrids are particularly susceptible. Suceptible turfgrassesĪll species of warm- and cool-season turfgrass are susceptible. Increase the height of cut and increase the air circulation. Avoid nitrogen application when the disease is active. Use low amounts of nitrogen, moderate amounts of phosphorous and moderate to high amounts of potash. ControlĬorrect water problems don't over-fertilize. Webbing may be evident early in the morning. Augustinegrass, patches appear straw-colored. In bermudagrass, centipede, and ryegrass, patches are brown. Leaf blades or sheaths are blighted in circular patches measuring inches to feet across. Excess soil moisture, extended leaf wetness, and/or high levels of nitrogen increase severity of the disease. Brown patch is favored by high relative humidity during the day and a minimum temperature of 65 degrees F at night. The most favorable conditions for disease development usually occur from late April through October. Augustinegrass, zoysiagrass, bentgrass, ryegrass, tall fescue, centipede and bermudagrass. The disease can infect all species of warm- and cool-season turfgrasses, including St. Alfredo Martinez, Extension Plant Pathologist Instead of filmed shots, a montage can also be formed out of still images. An old cop, for example, might be telling the story of his first year on the force and how over-the-top his methods were as he tells the story, the viewer would see a montage of the officer stepping over the line with suspects in various situations. If the montage is not set to music, there might be a character narrating what’s going on. For example, a montage might show a young couple going through a series of increasingly intimate dates while a romantic song plays in the background. In a musical montage, the shots are accompanied by a song that somehow fits with the theme of what’s being shown. There are an infinite number of different types of montages, but three of the most common are: a. We can call this “literary montage.” However, the term usually refers to film rather than literature. Sometimes, people use the word “montage” more loosely to mean any collection of small, discrete elements in a story or poem. Without using any words, the filmmaker shows us that this inventor is working intensely on his latest project. This is usually used to advance the plot in some way without showing all the detail of what’s going on – for example, you might show a series of quick shots in which an inventor is scribbling at his desk, then poring over a book on the train, then staring intently at a computer screen. Montage is a filmmaking technique that uses a series of short images, collected together to tell a story or part of a story. I usually give them at least a week to return orders. Window shopping the scholastic book club flyer gets the kids excited about the books, which in return increases the number of book orders you will have that month. When a child seems uninterested I always give them a suggestion or two to get them hooked on the idea of window shopping the flyer. I do this by simply giving students at least 5-10 minutes to preview the flyer and encourage them to circle books that look interesting to them. In my classroom, the anticipation starts to build when I first pass out the Scholastic book order flyers each month. By creative anticipation and excitement, your students will want to order more book from the Scholastic Book Club each month. Oh, the excitement! I couldn’t wait to get back to my classroom to see my beautiful new books laying on top of my desk. My teacher would tell us she would open the box while we were gone to specials and put our books on our desks. The janitor would bring the box into our classroom and we would all squeal with delight. In reality, it was probably like 2-3 weeks. We had to wait what seemed like months to get those precious books. The anticipation of the book box arrival was real too. Secret # 2 Create anticipation and Excitement in your classroom It is a great way to give them the opportunity to decide what types of books they like, and the types of books they WANT to own for themselves. When you use Scholastic Book Clubs in your classroom you are showing them how much you value reading and books. The first secret to increasing your Scholastic Book Club order it to create a love for books in your classroom. That is still a feeling I treasure today. That control was part of the reason I learned to love books so much. That small amount of decision-making power made me feel in control of my reading choices. So, this was truly the first time I had the power to look at an assortment of books and permission with a very tiny budget from mom. Back in those days, my school didn’t have book fairs like we have today. I’ll never forget how big I felt when I got to pick out my own book. Just the simple act of handing out those bright, colorful Scholastic book club flyers instilled a love of books for me. How do your students know that it is a priority? By using Scholastic book club flyers in your classroom! YES, of course, creating a love of books is a priority in your classroom. This may be a “duh” moment for most of you. You may be asking yourself “How can I do that with my current students?” So, now that I am a little girl living in an adult body I still have that overwhelming love of books that my teachers instilled in me way back then. Does this sound familiar to you? Secret # 1 Create a Love for Books By the time we went back thru the list I was lucky to have 1-2 books picked out with money in hand to return to my teacher the next day. Usually, my wish list was about ten books deep before sitting down with mom later that night. Then the final stage was to fill out the back of the flyer with all of my wonderful book choices and take that bad boy home and begin the begging process with mom and dad. Then I’d intently read thru the book club flyer from cover to cover to discover many hidden treasures that didn’t initially jump out at me. You know a great book cover always means it is a great book. The first order of business once that book flyer was in my hands was to circle in bright red crayon the prettiest book covers. I’ve got 3 secret ways I increase my monthly Scholastic Book Club orders to share with you! I’m telling my age a little bit here, but we’re friends, right? So, no judgment, please. I wanted all of the books…not much has changed in the last thirty years. It felt like the world was at my fingertips. I loved it when my first grade teacher passed out our Scholastic Book Club order forms. I can still remember how the newspaper felt rough between my fingers and the smell of stale paper flyers filled my 1st-grade classroom. A quick walk down Scholastic Book Club memory lane |
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